张浩
教授，博士生导师
办公室：化学楼221
电话：0471-4994406
邮箱：haozhang@imu.edu.cn
教育背景
1993-1997：内蒙古师范大学化学与环境科学学院，获得学士学位
1997-2000：内蒙古工业大学化工学院，获得硕士学位
2000-2004：华东理工大学应用化学，获得博士学位
工作经历
2004-2006：日本奈良先端科学技术大学院大学 JSPS博士后
2006-2009：日本理化学研究所侯金属有机实验室 协力研究员
2009-至今：内蒙古大学化学化工学院教授
学术兼职
荣誉与奖励
2010年，入选内蒙古自治区“草原英才”计划
2012年，入选内蒙古自治区“新世纪321人才工程”第一层次人选
2015年，入选内蒙古自治区“草原英才”创新团队
研究领域
1. 金属有机化学主要开展应用于烯烃催化聚合、烯烃复分解的新型催化剂的分子设计和催化性能研究。
2. 有机合成方法学主要开展利用新型过渡金属催化剂进行高选择性有机合成新反应、新方法研究。
3. 高分子化学主要利用金属催化剂合成各种具有特殊性能、结构可调、可控的高分子材料
教学
主讲化学化工学院大三《有机化学A》、研究生《金属有机化学》
研究项目
1. “高活性、高稳定性的炔烃复分解催化剂的设计、合成以及在共轭高分子合成中的探索研究”， 国家自然科学基金，2014年1月-2017年12月，55万，负责。
2. “新型烯烃复分解催化剂的设计、合成以及在制备结构可控的高性能聚合物材料中的应用”，国家自然科学基金，2011年1月-2013年12月，20万，负责。
3. “聚乙烯醇特种纤维应用基础研究产业创新人才团队” 内蒙古党委组织部，2015年11月-2018年11月，50万，负责。
4. “烯烃复分解催化剂的设计，合成以及应用”，教育部科学技术研究重点项目，2011年1月-2013年12月，6万，负责。
5. “烯烃聚合、复分解催化剂的设计，合成以及应用”， 内蒙古大学高层次引进人才科研启动基金项目，2011年1月-年12月，100万，负责。
6. “新型烯烃复分解催化剂的设计、合成以及应用”，内蒙古自然科学基金， 2011年1月-2013年12月，3万，负责 。
7. “内蒙古自治区“草原英才”，内蒙古党委组织部，2011年1月，15万，负责。
8. 内蒙古自治区优势资源高效清洁转化技术科技创新团队，30万，2011年1月-2013年12月 ，骨干参与，内蒙古自治区科技厅
9. 内蒙古大学煤化学催化与绿色化学材料创新团队，80万，2011年1月-2013年12月 ，骨干参与，内蒙古大学科技创新团队。
代表性成果
论文：
1. Hao Zhang, Kotohiro Nomura*, “Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide) titanium(IV) Complex - MAO Catalyst System”, J. Am. Chem. Soc. 2005,127, 9364-9365.
2. Liu, Y., Teng, Q., Hu, J., Sun, R., Zhang Hao*. Ferrocenyl-based unsymmertrical azines as multisignaling sensors for Hg2+, Cu2+ in aquenous environment. Sensors and Actuators B: Chemical, 2016, 234, 680-690.
3. Liu, Y., Teng Q., Hu J., Zhang Hao.*Ferrocenyl-based Thioethers and Sulphones as Optical, and Electochemical Sensors for the Differential Detection of Hg2+and Cu2+ ions. Sensors and Actuators B: Chemical, 2017, 166-174.
4. Ranfeng Sun, Huangdong Wang, Jianfeng Hu, Jiudong Zhao, Hao Zhang*, “Pyridine-phosphinimine ligand-accelerated Cu(I)-catalyzed azide-alkyne cycloaddition for preparation of 1-(pyridin-2-yl)-1,2,3-triazole derivatives”, Organic & Biomolecular Chemistry, 2014,12,5954-5963.
5. Hao Zhang*, Yuan Yao, Ranfeng Sun, Chen Sun, Fang Liu, Youran, Liu, Mei Guo, Sunan Wang, Kaiyuan You, “Thermally stable pseudo-third-generation Grubbs ruthenium catalysts with pyridine-phosphinimine ligand”, Catalysis Communications, 2014,49,43-46.
6. Hao Zhang, Yunjie Luo, Zhaomin Hou*, “Scandium-Catalyzed Syndiospecific Copolymerization of Styrene with Isoprene”, Macromolecules, 2008,41, 1064-1066.
7. Hao Zhang, Shohei Katao, Kotohiro Nomura*, Jiling Huang*, Synthesis ofNonbridgedhlaf-titanocenes containing phenoxy-imine ligands and their use in catalysis for olefin polymerization”. Organometallics, 2007,26, 5967-5977.
8. Hao Zhang, Doo-Jin Byun, and Kotohiro Nomura*, “Tuning the active species from syndiospecific styrene polymerisation to ethylene/styrene copolymerisation by (aryloxo)(cyclopentadienyl)titanium complexes - MAO catalysts”, Dalton Trans. 2007,18.1802-1806.(cover article).
9. Hao Zhang, Kotohiro Nomura*, Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide) titanium(IV) Complex - MAO Catalyst System: Effect of Anionic Ancillary Donor Ligand”, Macromolecules, 2006, 39, 5266-5274.
10. Qiang Teng, Jianfeng Hu, Li Ling, Ranfeng Sun, Junyang Dong, Shufeng Chen,Hao Zhang*, “Copper-catalyzed direct alkylation of 1,3-azoles with N-tosylhydrazones bearing a, ferrocenyl group: a novel method for the synthesis of ferrocenyl-based ligands”, Organic & Biomolecular Chemistry, 2014，7721-7727.
11. Kotohiro Nomura,* Hao Zhang, and Doo-Jin Byun, “Factors Affecting Product Distributions in Ethylene/Styrene Copolymerization by (Aryloxo)(cyclopentadienyl)titanium Complexes - MAO Catalyst Systems”, J. Polym. Sci. PartA: Polym. Chem., ,2008, 46, 4162-4174.
12. Hao Zhang, Jun Ma, Yanlong Qian, Jiling Huang*, “Synthesis and Characterization of Cyclopentadienylchromium Complex Bearing Pendant Pyridine Group as Catalyst for Ethylene Polymerization”, Organometallics.2004,23, 5681-5688.
13. Xueqin Sun, Jun Xie, Hao Zhang, Jiling Huang*, “Various silyl-substituted cyclopentadienyl titanium complexes [CpSi(CH3)2X]TiCl3 as catalysts for syndiotactic polystyrene”, Eur. Polym. J. 2004,40, 1903-1908.
14. Yanlong Qian*, Hao Zhang, Junxia Zhou, Wei Zhao, Xueqin Sun, Jiling Huang*, “Synthesis and polymerization behavior of various substituted half-sandwich titanium complexes Cp´ TiCl2(OR*) as catalysts for syndiotactic polystyrene”, J. Mol. Catal. A: Chem.2004, 208(1-2), 45-54.
15. Yanlong Qian*, Jiling Huang, Muhammad D.Bala, BingLian, Hao Zhang,Hao Zhang “Synthesis, Structures, and Catalytic Reactions of Ring-Substituted Titanium(IV) Complexes”,Chem. Rev. 2003,103(7), 2633-2690.
16. Quanling Suo*, Hao Zhang, Yibing Wang, Li Wang, Linhong Wen, Xuebing Leng, “Synthesis and structural characterization of {μ3-H(Ph)C=C}FeCo2(CO)7dppm (dppm=Ph2PCH2PPh2) and {μ3-H(Ph)C=C}FeCo2(CO)9-nLn[L=PPh3(n=1,2),AsPh3(n=1)]”, J. Organomet. Chem.2001, 63, 87-93.
17. H. Chai, J. F. Hu, Q. Shi, H. Zhang*, Synthesis and Chiroptical Properties of Helical Polyallenylferrocenes, J Polym Sci Pol Phys, 2017, 55, 2663-2669
18. L. Ling, J. Cao, J. F. Hu and H. Zhang*, Copper-catalyzed N-alkylation of indoles by Ntosylhydrazones, RSC Adv, 2017, 7, 27974-27980.
19. L. Ling, J. F. Hu, Y. H. Huo, H. Zhang*, Synthesis of ferrocene-based phosphine ligands via Cu-catalyzed reductive coupling of ferrocenyl ketone-derived tosylhydrazones and H-phosphorus oxides, Tetrahedron, 2017, 73,86-97.
20. J. Y. Dong, Y. F. Liu, J. F. Hu, Q. Teng, J. H. Cheng, Y. Luo, and H. Zhang*, Synthesis of Ferrocenyl-Based Unsymmetrical Azines via a Simple Reaction of Aldehydes with Ketone-Derived N‑Tosyl Hydrazones and the Evaluation of the Extent of Conjugation in the Molecule, Organometallics,2017, 36, 3215-3225.
21. J. Y. Dong, Y. F. Liu, J. F. Hu, H. Baigude, H. Zhang*, A novel ferrocenyl-based multichannel probe for colorimetric detection of Cu(II) and reversible fluorescent “turn-on” recognition of Hg(II) in aqueous environment and living cells, Sensors and Actuators B, 2018, 255, 952-962.
22. Teng, Q., Liu, Y., Hu, J., Chai, H., Li, K., Zhang, H.*, Straightforward synthesis of ferrocenyl-based thioether and application as chemosensor for Hg2+ ion, Tetrahedron,2016,72, 3890-3897.
23. Hao Zhang*, Fang Liu, Jing Cao, Li Linga, and Ran-feng Sun, Ferrocene-containing polymers synthesized by acyclic diene metathesis (ADMET) polymerization, Chinese Journal of Polymer Science,2016, 34, 242-252.
24. Ranfeng Sun, Chunjuan Liu, Hao Zhang*, and Qingmin Wang, Benzoylurea Chitin Synthesis Inhibitors, J. Agric. Food Chem. 2015, 63,6847-6865.
25. Hao Zhang*, Kotohiro Nomura, Ligand effect in syndiospecific styrene polymerization and ethylene/styrene copolymerization by some nonbridged half-titanocenes containing anionic donor ligands,Studies in Surface Science and Catalysis, 2006,161, 145-152.
26. Yanlong Qian*, Hao Zhang, Jiling Huang, Synthesis and Characterization of Cyclopentadienylchromium Complexes Bearing Pendant o-Me2N-C6H4-C(CH3)(CH3)- Group as Catalysts for Ethylene Polymerization, Chinese Journal of Catalysis, 2003,21(7), 487-488.
27. Quanling Suo*, Hao Zhang, Yibing Wang, Jiehui Yan, Liming Han, Linghong Weng, Xuebing Leng, Synthesis and Molecular Structure of Substituted Derivatives of the Mixed-metal Carbonyl Clusters Bearing µ3-vinylidene Moiety, Chinese Journal of Inorganic Chemistry 2003, 19(5), 506-508.
28. Hao Zhang, Jiling Huang, Yanlong Qian*, Progress in Synthesis of Chromium Catalysts and Their Application in Olefin Polymerization， Chinese Journal of Organic Chemistry 2003, 22(12), 981-989.
29. Hao Zhang, Quanling Suo*, Yibing Wang, LiWang, Linghong Weng, Xuebing Leng， Synthesis and Crystal Structure of (μ3-S)FeCo2(CO)7dppfe，Acta Phys.-Chim. Sin. 2002, 18(8), 746-749.
